Building a Word Document Using SQL Server Data

In this walkthrough, you will first create a Microsoft® Office Word 2003 document that contains bookmarks as the location for inserting text retrieved from the Microsoft SQL Server Northwind sample database. You will then use ADO.NET to connect to and retrieve the data. You'll insert the data in the Word document at the specified bookmark.

http://msdn.microsoft.com/en-us/library/office/aa192487(v=office.11).aspx

http://www.codeproject.com/Articles/96969/A-Dynamic-Word-Template-that-Generates-information